tlooto
Sign up
N-Heterocyclic Carbenes in Organic and Inorganic ChemistrySynthetic Organic Chemistry MethodsOrganometallic Complex Synthesis and Catalysis

Synthesis of an O,N,O-C Multidentate Ligand Bearing an N-Heterocyclic Carbene Towards Heterobimetallic Complexes

Noriyuki Suzuki, Muneyasu Hara, Yuxuan Gao, Yumiko Suzuki

2026.3.20Compounds

DOI: 10.3390/compounds6010024

Abstract

A novel multidentate ligand with an O,N,O-tridentate ligand moiety and an N-heterocyclic carbene (NHC) was synthesized. Its palladium complex, in which the NHC part coordinates to the palladium atom, was synthesized and structurally characterized. The O,N,O-part coordinated to an early transition metal such as titanium. The Ti-Pd heterobimetallic complex was observed in solution.

Citation format

SUZUKI, Noriyuki, et al. Synthesis of an O,N,O-C multidentate ligand bearing an n-heterocyclic carbene towards heterobimetallic complexes. Compounds, 2026, 6(1): 24.