tlooto
Sign up
Chemistry

Methanolysis of Dimethyl (1-Diazo-2-oxopropyl) Phosphonate: Generation of Dimethyl (Diazomethyl) Phosphonate and Reaction with Carbonyl Compounds

S. Ohira

1989.2.1SYNTHETIC COMMUNICATIONS

DOI: 10.1080/00397918908050700

tlooto Summary

Researchers transformed dimethyl (1-diazo-2-oxopropyl) phosphonate to dimethyl (diazomethyl)—phosphonate, generating enol ether or alkyne without isolation.

Abstract

Abstract Dimethyl (1-diazo-2-oxopropyl) phosphonate (3) was transformed to dimethyl (diazomethyl)—phosphonate (4), which was used for the synthesis of enol ether or alkyne without isolation.

Citation format

OHIRA, S. Methanolysis of dimethyl (1-diazo-2-oxopropyl) phosphonate: Generation of dimethyl (diazomethyl) phosphonate and reaction with carbonyl compounds. SYNTHETIC COMMUNICATIONS, 1989, 19: 561–564.