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ChemistryMaterials ScienceMedicine

Single-atom catalysis of CO oxidation using Pt1/FeOx.

B. Qiao, Aiqin Wang, Xiaofeng Yang, L. Allard, Zheng Jiang, Yitao Cui, J. Liu, Jun Li, Tao Zhang

2011.8.1Nature Chemistry

DOI: 10.1038/nchem.1095

tlooto Summary

Density functional theory calculations show that the high catalytic activity correlates with the partially vacant 5d orbitals of the positively charged, high-valent Pt atoms, which help to reduce both the CO adsorption energy and the activation barriers for CO oxidation.

Abstract

Abstract is not available.

Citation format

QIAO, B., et al. Single-atom catalysis of CO oxidation using pt1/feox. Nature Chemistry, 2011, 3 8: 634–41.